Predicting reflectivity and emissivity of porous media
is a long-standing problem important to many fields of science. The approach we are
taking combines particle scattering submodels with a theoretically based derivation of the
overall reflectivity.The concept is illustrated at the right
and follows the derivation of Hapke [??]. The fundamental problem is that the
radiative transport equation (which is a differential-integral equation) is too difficult
to solve, even numerically, except for highly idealized situations. However, a
reasonable approximation to its solution can be derived according to the following logic.
If we have a ray of light impinging on a semi-infinite, homogeneous body, adding a
differential layer of material to the surface of the body should not affect its radiative
properties. If we write expressions for the leading terms that are affected by
adding such a layer, we know that they must sum to zero (no effect). For example,
the differential layer attenuates light (see panel a) by absorption both as the incident
beam passes through it and as it is reflected from the underlying material back to the
detector. The effect of this attenuation is a decrease in signal. However, the
differential layer also scatters light directly to the detector (see panel b), which has
the effect of increasing the signal. A portion of the scattered light is also
reflected off the underlying material and into the detector (panel c). The first
five effects are indicated in the figure.
The sum of all these contributions must be zero.
Mathematically writing these effects down and forcing them to zero returns another
differential equation to be solved, but it is far less difficult than the original
radiative transport equation.
This is the conceptual basis for our emissivity model. The
mathematical details are available elsewhere.