Dielectric Increments & Dervied Dipole Moments for some Amino Acids & Glycine Peptide Chains in Aqueous Solution at 25°C |
Sample |
Dielectric Increment δ |
Debye Units (from eqn 3.5*) |
References |
α-Alanine |
23.2 |
15.9 |
13 |
|
27.7 |
17.4 |
14 |
l-Asparagine |
28.4 |
17.6 |
14 |
|
20.4 |
14.9 |
16 |
l-Aspartic Acid |
27.8 |
17.4 |
14 |
d-Glutamic Acid |
26 |
16.8 |
14 |
l-Glutamine |
20.8 |
15.1 |
16 |
Glycine |
22.6 |
15.7 |
13 |
|
26.4 |
17.0 |
14 |
l-α-Leucine |
25 |
16.5 |
14 |
Glycine Dipeptide |
70 |
27.6 |
14 |
|
70.5 |
27.7 |
17 |
Glycine Tripeptide |
113 |
35.1 |
13 |
|
128 |
37.3 |
17 |
Glycine Tetrapeptide |
159 |
41.6 |
13 |
Glycine Pentapeptide |
215 |
48.4 |
13 |
Glycine Hexapeptide |
234 |
50.5 |
13 |
Glycine Heptapeptide** |
290 |
56.2 |
5 |
Taken from Pethig p.80 |
* Equ 3.5: µ = 3.30
δ01/2
** In 5.14 molar urea
Reference 5: J Wyman,
J. Am. Chem. Soc.,
14 1 (1959)
Reference 13: J. Wyman and T. L. McMeekin,
J. Am. Chem. Soc.,
55, 908 (1933)
Reference 14: P. Devoto,
Gazz. Chim. Ital., 60, 520 (1930);
61, 897 (1931);
64, 76 (1934)
Reference 16: H. Greenstein and J Wyman,
J Am. Chem. Soc.,
58, 463 (1936)
Reference 17: A. Cavallaro,
Arch. Sci. Biol.,
20, 567 (1934)