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Dielectric relaxation time values for water bound to various biomolecules

Molecule τ (s) Remarks Reference
Horse haemoglobin 2 x 10-10 22% solution, 25 ºC 173
Lysozyme 5 x 10-10 powder, 33% H2O, 25 ºC 175
Bovine serum albumin 1.6 x 10-9 1% solution, 25 ºC 171
Egg albumin 5.3 x 10-10 1% solution, 25 ºC 171
Proline, hydroxyproline ~10-10 2 M solutions, 20 ºC 179
ε-Amino-n-caprioc acid
Starch (a) 1 x 10-9
(b) 2 x 10-10
powder, 25 ºC
(a) 15% H2O, (b) 20% H2O
180
D-Glucose 2 x 10-10 2 M solution, 5 ºC 181
Liquid water 8.2 x 10-12 25 ºC 158
Ice 2.8 x 10-5
2.4 x 10-6
-3.8 ºC
extrapolated to 25 ºC
159
Pethig p.144

Reference 158: C. H. Collie, J. B. Hasted, and D. M. Ritson, Proc. Roy. Soc. (London), 60, 145 (1948)
Reference 159: R. P. Auty and R. H. Cole, J. Chem. Phys., 20, 1303 (1952)
Reference 171: E. H. Grant, Ann. N.Y. Acac. Sci., 125, Art. 2, 418 (1965)
Reference 173: B. E. Pennock and H. P. Schwan, J. Phys, Chem., 73, 2600 (1969)
Reference 175: S. C. Harvey and P. Hoekstra, J. Phys. Chem., 76, 2987 (1972)
Reference 179: J. C. W. Shepherd and E. H, grant, Ii> Proc. Roy. Soc. (London(, A307, 345 (1968)
Reference 180: P. Abadie, R. Charonniere, A. Gidel, P. Girard, and A. Guilbot, J. Chim. Phys., 50, C46 (1953)
Reference 181: M. J. Tait, A. Suggett, F. Franks, P. A. Quickenden, and S. Ablett, J. Solution Chem., 1, 131 (1972)
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